|
|
S-adenosyl-L-methionine + 6-hydroxytryprostatin_B <=> S-adenosyl-L-homocysteine + tryprostatin_A + H+
|
2.1.1.293
6-hydroxytryprostatin B O-methyltransferase
|
–
|
| |
BRENDA:
BR50795
KEGG:
R10588
MetaCyc:
RXN-14927
|
|
|
|
tryprostatin_A + reduced_[NADPH-hemoprotein_reductase] + O2 <=> fumitremorgin_C + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.19.71
fumitremorgin C synthase
|
–
|
| |
MetaCyc:
RXN-14415
|
|
|
|
dimethylallyl_diphosphate + brevianamide_F <=> diphosphate + tryprostatin_B
|
2.5.1.106
tryprostatin B synthase
|
–
|
| |
BRENDA:
BR50540
KEGG:
R10340
MetaCyc:
RXN-14418
|
|
|
|
L-tryptophan + L-proline + ATP <=> brevianamide_F + ADP + phosphate + H+
|
6.3.3
|
–
|
| |
MetaCyc:
RXN-15642
|
|
|
|
demethoxyfumitremorgin_C <=> fumitremorgin_C
|
not assigned
|
–
|
| |
MetaCyc:
RXN-15644
|
|
|
|
tryprostatin_B + reduced_[NADPH-hemoprotein_reductase] + O2 <=> demethoxyfumitremorgin_C + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.19.71
fumitremorgin C synthase
|
–
|
| |
MetaCyc:
RXN-14416
|
|
|
|
tryprostatin_B + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 6-hydroxytryprostatin_B + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.118
tryprostatin B 6-hydroxylase
|
–
|
| |
MetaCyc:
RXN-14413
|
|
